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Lithium chloride

CAS number : 7447-41-8

Molecular weight :42.39

Molecular formula/chemical symbol :LiCl

Description :

Lithium chloride is a chemical compound with the formula LiCl. The salt is a typical ionic compound, although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83g/100 mL of water at 20 °C) and its hygroscopic properties.

The salt forms crystalline hydrates, unlike the other alkali metal chlorides. Mono-, tri-, and pentahydrates are known. It also absorbs up to four equivalents of ammonia. As with any other ionic chlorides, solutions of lithium chloride can serve as a source of chloride ion, e.g. forming a precipitate upon treatment with silver nitrate:

LiCl + AgNO3 → AgCl + LiNO3

Lithium chloride

Preferred IUPAC name[hide]

Lithium chloride

Systematic name[hide]

Lithium(1+) chloride

Identifiers

CAS number

7447-41-8 YesY

PubChem

433294 YesY

ChemSpider

22449 YesY= ?

UNII

G4962QA067 YesY

UN number

2056

MeSH

Lithium+chloride

ChEBI

CHEBI:48607 YesY

ChEMBL

CHEMBL69710 N

RTECS number

OJ5950000

Jmol-3D images

Image 1

Properties

Molecular formula

LiCl

Molar mass

42.394(4) g/mol

Appearance

white solid
hygroscopic

Density

2.068 g/cm3

Melting point

605 °C

Boiling point

1382 °C (decomp)

Solubility in water

55 g/100 mL (20 °C)
128.3 g/100 mL (100 °C)

Solubility

highly soluble in pyridine, nitrobenzene
4.1 g/100 mL (acetone)
17 g/100 mL (methanol)
2.5 g/100 mL (ethanol)

Refractive index (nD)

1.662

Structure

Coordination
geometry

Octahedral

Molecular shape

Linear (gas)

Dipole moment

7.13 D (gas)

Thermochemistry

Std enthalpy of
formation
ΔfHo298

-9.638 kJ/g

Specific heat capacity, C

1.132 J/(g K)

Hazards

MSDS

External MSDS

EU Index

Not listed

Flash point

Non-flammable

Related compounds

Other anions

Lithium fluoride
Lithium bromide
Lithium iodide

Other cations

Sodium chloride
Potassium chloride
Rubidium chloride
Caesium chloride

Supplementary data page

Structure and
properties

n, εr, etc.

Thermodynamic
data

Phase behaviour
Solid, liquid, gas

Spectral data

UV, IR, NMR, MS

 N (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

USES :

For air-conditioning

Used as a flux, desiccant, chemical reagents

Used in making fireworks, dry batteries and lithium

Keywords:Electronic chemicals

Report :

Product name

Lithium chloride

CAS7447-41-8

Description

Colorless cubic crystals

TEST ITEMS

TEST RESULTS

LiCl

≥99.3

Na+K

≤0.003

SO42-

≤0.003

Li2CO3

≤0.025

Fe2O3

≤0.002

BaCl2

≤0.03

H2O

≤0.60