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Lithium peroxide

CAS number : 12031-80-0

Molecular weight :45.88

Molecular formula/chemical symbol :Li2O2

Description :

Lithium peroxide is the inorganic compound with the formula Li2O2. This solid was deployed to remove CO2 from the atmosphere in the Apollo spacecraft.

Lithium peroxide

Other names[hide]

Dilithium peroxide, Lithium (I) peroxide

Identifiers

CAS number

12031-80-0 

PubChem

25489

ChemSpider

23787 YesY

Jmol-3D images

Image 1

Properties

Molecular formula

Li2O2

Molar mass

45.881 g/mol

Appearance

fine, white powder

Odor

odorless

Density

2.31 g/cm3

Melting point

195 °C

Boiling point

Decomposes to Li2O

Solubility in water

soluble

Solubility

insoluble in alcohol

Structure

Crystal structure

hexagonal

Thermochemistry

Std enthalpy of
formation
ΔfHo298

-13.82 kJ/g

Hazards

EU classification

not listed

 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

 

USES :

It is used in air purifiers where weight is important e.g. spacecraft to absorb carbon dioxide and release oxygen in the reaction:

2Li2O2 + 2CO2 → 2Li2CO3 + O2

It absorbs more CO2 than does the same weight of lithium hydroxide and offers the bonus of releasing oxygen.

Keywords:Electronic chemicals

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