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Lithium hexafluorophosphate

CAS number : 21324-40-3

Molecular weight :151.90

Molecular formula/chemical symbol :LiPF6

Description :

Lithium hexafluorophosphate is an inorganic compound with the formula LiPF6. This white crystalline powder is used in commercial secondary batteries, an application that exploits its high solubility in nonpolar solvents. Specifically, solutions of lithium hexafluorophosphate in propylene carbonate with dimethoxyethane serves as an electrolyte in lithium batteries. This application also exploits the inertness of the hexafluorophosphate anion toward strong reducing agents, such as lithium metal.

LiPF6 also catalyses the tetrahydropyranylation of tertiary alcohols.

Lithium hexafluorophosphate

IUPAC name[hide]

lithium hexafluorophosphate

Identifiers

CAS number

21324-40-3 YesY

PubChem

23688915

ChemSpider

146939 YesY

Jmol-3D images

Image 1

Properties

Molecular formula

LiPF6

Molar mass

151.905 g/mol

Appearance

white powder

Density

1.5 g/cm3

Melting point

200 °C

Solubility in water

soluble

Hazards

MSDS

External MSDS

GHS pictograms

The corrosion pictogram in the Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

GHS signal word

DANGER

GHS hazard statements

H314

GHS precautionary statements

P280, P310, P305+351+338

EU Index

Not listed

R-phrases

R22, R24, R34

S-phrases

S26, S36, S37, S39, S45

Flash point

Non-flammable

Related compounds

Other anions

Lithium tetrafluoroborate

Other cations

Sodium hexafluorophosphate
Potassium hexafluorophosphate
Ammonium hexafluorophosphate

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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

USES :

Electrolyte material of the lithium-ion battery, rechargeable lithium-ion battery.

Keywords:Electronic chemicals

Report :

Product name

Lithium hexafluorophosphate

CAS21324-40-3

Description

White powder

TEST ITEMS

TEST RESULTS

LiPF6

≥99.9%

HO

≤20ppm

Free acid (hydrofluoric acid)

≤100ppm

Al

≤5 ppm

Cr

≤5 ppm

Fe

≤5 ppm

Mg

≤5 ppm

Cu

≤5 ppm

Ca

≤2 ppm

Pb

≤2 ppm

Na

≤5 ppm