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Cesium chloride

CAS number : 7647-17-8

Molecular weight :168.37

Molecular formula/chemical symbol :CsCl

Description :

Caesium chloride (cesium chloride in North America), is the inorganic compound with the formula CsCl. This colorless solid is an important source of caesium ions in a variety of applications. Its crystal structure forms a major structural type where each caesium ion is coordinated by 8 chlorine ions. Caesium chloride crystals are thermally stable, but easily dissolve in water and concentrated hydrochloric acid, and therefore gradually disintegrate in the ambient conditions due to moisture. Caesium chloride occurs naturally in mineral waters and as an impurity in carnallite (up to 0.002%), sylvite and kainite. Less than 20 tonnes of CsCl is produced annually worldwide, mostly from a caesium-bearing mineral pollucite

Caesium chloride is colorless in the form of large crystals and white when powdered. It readily dissolves in water with the maximum solubility increasing from 1865 g/L at 20 °C to 2705 g/L at 100 °C. The crystals are very hygroscopic and gradually disintegrate at ambient conditions. Caesium chloride does not form hydrates.

Solubility of CsCl in water

Т (°C)

0

10

20

25

30

40

50

60

70

80

90

100

S (wt%)

61.83

63.48

64.96

65.64

66.29

67.50

68.60

69.61

70.54

71.40

72.21

72.96

Caesium chloride

IUPAC name

Caesium chloride

Other names

Cesium chloride

Identifiers

CAS number

7647-17-8 YesY

ChemSpider

22713 YesY

UNII

GNR9HML8BA YesY

EC number

231-600-2

Jmol-3D images

Image 1

SMILES

            [Cs+].[Cl-]

InChI

            InChI=1S/ClH.Cs/h1H;/q;+1/p-1 YesY
Key: AIYUHDOJVYHVIT-UHFFFAOYSA-M YesY


InChI=1/ClH.Cs/h1H;/q;+1/p-1
Key: AIYUHDOJVYHVIT-REWHXWOFAO

Properties

Molecular formula

CsCl

Molar mass

168.36 g/mol

Appearance

white solidhygroscopic

Density

3.99 g/cm3

Melting point

645 °C

Boiling point

1297 °C (vaporizes)

Solubility in water

1865 g/L[2]

Solubility

soluble in ethanol[3]

Band gap

8.35 eV (80 K)[1]

Refractive index (nD)

1.64[4]

Structure

Crystal structure

Caesium chloride (see text), Pm3m, space group No. 221, Pearson symbol cP2

Coordination
geometry

simple cubic (interpenetrating)

Related compounds

Other anions

Caesium fluoride
Caesium bromide
Caesium iodide
Caesium astatide

Other cations

Lithium chloride
Sodium chloride
Potassium chloride
Rubidium chloride

 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

USES :

Preparation of metal cesium and cesium-containing single crystal raw material,

Reagents for the analysis.

Keywords:Electronic chemicals

Report :

Product name

Cesium chloride

CAS7647-17-8

Description

white solidhygroscopic

TEST ITEMS

TEST RESULTS

CsCl

≥99.99

≥99.9

≥99.5

≥99.0

Na

≤0.005

≤0.01

≤0.02

≤0.10

K

≤0.0005

≤0.001

≤0.01

≤0.05

Rb

≤0.001

≤0.002

≤0.01

≤0.2

Ca

≤0.001

≤0.005

≤0.01

≤0.03

Mg

≤0.003

≤0.005

≤0.01

≤0.02

Fe

≤0.0005

≤0.001

≤0.001

≤0.002

Al

≤0.001

≤0.002

≤0.005

≤0.02

Pb

≤0.0001

≤0.0005

≤0.001

≤0.005

Ni

≤0.0001

≤0.001

≤0.001

≤0.05

SO4

---

---

≤0.01

≤0.05